Switzerland is very well connected to other countries through a tight net of trains, buses and ferries. Read this post to get an overview on which destinations in Europe and North Africa you can reach easily without plane.
Italy
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Check out the destinations in Italy here.
France
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Check out the destinations in France here.
Germany
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Check out the destinations in Germany here.
Austria
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Check out the destinations in Austria here.
Spain
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Check out the destinations in Spain here.
Portugal
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Check out the destinations in Portugal here.
Belgium
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Check out the destinations in Belgium here.
Netherlands
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Check out the destinations in the Netherlands here.
Great Britain
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Check out the destinations in Great Britain here.
Ireland
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Check out the destinations in Ireland here.
Denmark
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Check out the destinations in Denmark here.
Sweden
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Check out the destinations in Sweden here.
Norway
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Check out the destinations in Norway here.
Overview of Night Train destinations in Europe
Overview of all destinations from SimpleTrain
Check out the full overview of destinations reachable by train on this interactive map by SimpleTrain and book directly on simpletrain.ch.